《[化学]路博润金属加工液培训资料.ppt》由会员分享，可在线阅读，更多相关《[化学]路博润金属加工液培训资料.ppt（132页珍藏版）》请在三一办公上搜索。
1、Metalworking Additives金属加工添加剂,October 2012,Agenda 议程,Introduction 概况介绍Metalworking Capabilities and Support 金属加工系列产品线和技术支持Product Offering and Formulation Advices 产品介绍和配方举例Questions 问题,Sulfurized EP Additives,Traditional Soluble Oil Emulsifier硫系极压剂及乳化剂产品,Waterbased Additives,Emulsifier Expertise,Spe
2、ciality Polymeric Esters水基添加剂、乳化剂和聚合酯,Water based Additives,Corrosion Inhibitor Expertise,水基防锈及防腐蚀剂Biocides杀菌剂,Rust Preventives,Water based Corrosion Inhibitors防锈剂,Rust Preventives,Natural Sulfonate supply,Thixotropic Gelled Sulfonate防锈剂、磺酸盐,Global Support 全球技术支持,Technical laboratories 技术实验室Wickliff
3、e,OH USABrecksville,OH USAHazelwood,EnglandSpartanburg,SC USAMetalworking Research&Technical Service金属加工产品研发和技术支持Hamburg,Germany 德国汉堡Metalworking Technical Support 金属加工产品技术支持Shanghai,China 上海Metalworking Technical Support 金属加工产品技术支持,Shanghai Metalworking Resources上海实验室配置和评价方法,ProcedureProperty Evalu
4、atedIP287 Filter Paper Chip Breakpoint 防锈/滤纸铁屑法IP263Emulsion Stability 乳化安定性IP 311Concentrate Storage Stability 储存稳定性IP312Foam Test Shaking Method 泡沫试验ASTM D 455Kinetic Viscosity 黏度测定Lubrizol Pump Test Foam Test 路博润泡沫试验MicroTap II Lubricity 润滑性评定/攻丝扭矩Mod.Timken Fish Tank Bacteria Resistance 抗菌性试验,If
5、 need technical service for our customers,pls fill in TSRs first.,MicroTap,Foam Rig,Additives Applications Capabilities路博润添加剂的应用领域,Lubrizol Metalworking Additives,Metalworking AdditivesProduct Offering for Water based Products水基金属加工液产品介绍,Metalworking Additives金属加工添加剂,Water Based Water Miscible 水基或水溶
6、性产品Aqueous Fluid System 应用于水基体系Generally Supplied as Concentrate for Dilution in Water 通常以浓缩液的形态供应，使用时以水稀释Sub Categories 这类产品包括Soluble Oil 乳化油Synthetic 全合成液Semi Synthetic 半合成液,Product Categories 产品,Emulsifier ComponentsEmulsifier Packages Hong Jing 乳化复合剂洪泾介绍Extreme Pressure AdditivesLubricity Additi
7、ves 润滑剂Rust PreventivesCorrosion Inhibitors 防锈剂Industrial MetalworkingBiocides 杀菌剂,Lubricity Additives for water miscible fluids水基润滑剂,Lubricity/EP agents 润滑/极压剂,ADDOSAN ESTEP 206TMP-Ester of Castoroil and Oleicacid 是以蓖麻油和油酸为原料的TMP的酯Addosan ESTEP 206 is used as an EP-additive in water miscible metal
8、working fluids,especially for Al-processing.Typical treat levels in the concentrate should be 5-10%.该产品可用于水基配方中做极压剂，特别适合铝加工。加量510%For the machining of steel the addition should be between 5 and 20%to the concentrate,depending on the requirements and the severity of the process 用于钢材加工时需要在浓缩液里加入520%，视
9、加工的剧烈程度而定。In non water based metal working fluids,Addosan ESTEP 206 is qualified for fine steel wire drawing in combination with P-EP and S-additives.在非水基的体系中它与含磷或含硫极压剂共用可用于细钢线的拉拔。Addosan ESTEP 206 can also be used as a fatty agent in non-water miscible metal working fluids.在非水溶性配方里可用作油性剂It is also
10、suitable for grinding processes where a good stability of the fatty component is required.在磨削加工中如果需要使用稳定性好的油性剂，可考虑使用该产品,Addosan Estep 206,Properties Colour颜色:ligth brown 浅棕色Acid value 酸值(mg KOH/g):max 10Viscosity 黏度(40 C):appr 85 mm/sTypical use level典型用量 Waterbased水基:5 10%Neat oils油基:1 2%(neat oils
11、:2%Estep 206+0.5%EPC 127-used for flute grinding 在油基配方中使用2%Estep 206+0.5%EPC 127可用于成管加工),BECROSAN E 2135 amine and boron free formulation with biocide配方举例：不含胺、不含硼的半合成液配方,BECROSAN E 2135 45%Addosan ESTEP 206 10%Naphthenic Base Oil 42%CONTRAM OF-G 2.5%CONTRAM J 30 D 0.5%An approx.8%emulsion of a prepa
12、ration of BECROSAN E 2135,performance ester(in particular Addosan ESTEP 206)in base oil(as above)works extraordinary well for general aluminium machining.上述配方以8%的稀释液用于铝加工具有非常突出的效果 Appearance 外观 visual目测 translucent 半透明 Emulsion stability 乳化安定性 visual after 24 hrs 0 ml oil/0 ml creampH value,5%in wat
13、er 5%水溶液的PH值 DIN 51 3699.1 Corrosion protection DIN 51 360 part 2 Note 0 at 4%vol 防锈,Semi Synthetic Aluminum铝加工半合成液润滑效果45%BECROSANE2135+环烷基油 VS 10%ADDOSANESTEP206+45%BECROSANE2135+环烷基油,High oil-Semi-Synthetic Packages与高含油半合成复合剂的复配配方,Performance 性能,Metalworking-Corrosion Inhibitors 防锈剂,Stop Rust,Becr
14、osan 2131 Technology,Trivial name:Triazinetrisaminohexanoic acid三嗪三氨基己酸 IUPAC:6,6,6-(1,3,5-triazine-2,4,6-triyltriimino)-trihexanoic acid,CAS-No.80584-91-4 MW:468.6 g/mol,Becrosan 2131 Technology,Applications应用Neutralized with alkali/alkanolamine performs as very effective corrosion inhibitor用碱/醇胺中和
15、后是非常有效的腐蚀抑制剂Applied in all types of water based systemsMetalworking fluids(Semi-synthetic and synthetic fluids)可以用于所有类型的水基体系金属加工液(半合成和合成液)High water based hydraulic fluids(HFC)可用于高水基液压液(HFC)Engine and other cooling systems 用于发动机和其他冷却体系,Becrosan 2131 Technology,Benefits优点Very effective corrosion inhi
16、bition高效防锈Does not form resinous films or gums on metals 不会在金属表面形成树脂或胶状膜Low foaming低泡沫No aluminum staining(depending on amine used)不会造成铝腐蚀Compatible with hard water up to 2000 ppm 耐硬水能力高达 2000 ppmCan be used for corrosion inhibition of multi-metal systems,might be improved by addition of Skosanor KS
17、P 24/531 and heptanoic/ison.Acid 可以用于含多种金属的体系，添加Skosanor KSP 24/531可提高防腐蚀效果PROVEN:No tendency to form nitrosamines(5f rule in US)不会生成亚硝胺Excellent air release良好的空气释放性能,Becrosan 2128 Technology,Trivial name:Tolylsulfonamidohexanoic acid对甲苯磺酰氨基己酸 IUPAC:4-Methylphenylsulfonylaminohexanoic acid,CAS-No.78
18、521-39-8 MW:285.0 g/mol,Becrosan 2128 Technology,Applications应用:Neutralized with alkali/alkanolamine performs as very effective corrosion inhibitor用碱/醇胺中和后是非常有效的腐蚀抑制剂Applied in all types of water based systems Metalworking fluids(Semi-synthetic and synthetic)可以用于所有类型的水基体系金属加工液(半合成和合成液)Water treatmen
19、t processes水处理过程Press waters水压系统Industrial cleaners工业清洗剂Off-shore lubricants海上石油/天然气钻探用润滑剂Water based hydraulic fluids水基液压液Water/glycol cooling systems(+KSP 24/531)水/乙二醇冷却体系（可加入 KSP 24/531提高抗腐蚀效果）,Becrosan 2128 Technology,BENEFITSVery effective corrosion inhibition for ferrous metals,cast iron,ferro
20、us alloys at a pH value of 8.pH值8时，对铁、铸铁和铁合金的防锈非常有效Easy handling,easy soluble,non dusting,odorless 容易使用，容易溶解,不会产生粉尘，无味 No sticky residues after water phase evaporation 水相挥发后无粘性残留物Low foaming低泡Compatible with hard water up to 2000 ppm耐硬水能力 2000 ppmNo staining on aluminum(depending on amine used)不会造成铝
21、变色No tendency to form nitrosamines不会生成亚硝胺Higher thermal stability than metal soaps比金属皂具有更好的热稳定性,Fully synthetic based on BECROSAN 2131全合成液的建议配方,20%Triethanolamine 三乙醇胺5%Monoethanolamine 单乙醇胺16%BECROSAN 21312,5%Isononanoic acid 异壬酸0,5%Skosanor KSP 5310,5%CONTRAM NFK55,5%Water 水DIN 51360 T2(Chip filte
22、r test)防锈（滤纸铁屑法）=2,5%class 0pH-value(3%in DI-water)pH值（在3%去离子水中）=9,2Foam behaviour(5%in 10dH-water)泡沫=70 ml 30 ml 0 mlReichert(5%in DI-water,100 m,1,5 kg)磨斑=30,6 mm/GM 100,Starting Formulation Grinding/Machiningmore severe machining用于更高负荷的磨削/切削配方,Semi synthetic based on BECROSAN 2131半合成配方,32,0%Base
23、oil 基础油8,0%ADDCONATE M 15,5%Triethanolamine 三乙醇胺2,0%Monoethanolamine 单乙醇胺7,5%BECROSAN 21282,0%BECROSAN 21312,5%TD 25/30 7,5%Coupling agents(fatty alcohol)偶合剂15,0%Water 水5,0%BECROSAN C656(fatty acid amide脂肪酸酰胺)2,5%CONTRAM ST-10,5%CONTRAM J 30 D Appearance 外观Clear,yellow 黄色透明Emulsion乳液Translucent 半透明D
24、IN 51360 T2(Chip filter test)防锈=2,5%class 0pH-value(3%in DI-water)pH=9,3,Use Of Alkanolamides In Metalworking金属加工液中链烷醇酰胺的应用,Emulsifier 做乳化剂Functions as a primary or secondary emulsifier in o/w metalworking formulations在水包油型乳化油配方中可做主乳化剂或助乳化剂使用Lubricity Additive 润滑剂Amides based on longer chained fatty
25、 acids enhance lubrication properties to a fluid基于长链脂肪酸的酰胺有助于提高体系的润滑效果Corrosion Inhibitor 防锈剂Fatty acid alkanolamides provide extra corrosion protection for ferrous metals脂肪酸的链烷醇酰胺对黑色金属有良好的防锈效果.,Fatty amides/esters 脂肪酸酰胺/酯,STRENGTH 优点Cheap corrosion inhibitors 是一种较便宜的防锈剂Post treatment application po
26、ssible 可现场添加Low classification level。Low toxicity profile 低毒性Some are liquid,easy to handle 有一些产品是液体的，易操作Used for semi-synthetic and soluble oil type fluids 可用于乳化油和半合成液,Fatty amides/esters 脂肪酰胺/酯,Performance 性能,ADDCONATE Starting FormulationSemi Synthetic建议起始配方半合成,ADDCONATE Starting FormulationSemi
27、Synthetic 建议起始配方半合成,Biocides杀菌剂,Biocide review:,Biocide review:,Micro-organisms like微生物喜欢A wet environment潮湿环境Temperature温度Dust尘土And certain elements as food stuff 以及某些可以作为食物的元素Which are given in allMETAL WORLKING FLUIDS这些在金属加工液中均可以得到满足,Biocide review:,Bactericides杀细菌剂,CONTRAM ST-1,N,N-methylenebism
28、orpholine N,N-亚甲基双吗啉CAS#5625-90-1,CONTRAM MBO,Oxazolidine,3,3-methylenebis5-methyloxazolidine 噁唑烷，3,3-亚甲基双5-甲基唑烷CAS#66204-44-2,Product Features 产品特性,CONTRAM ST-1Exceptional stability in MWF concentrates 在浓缩物中特别稳定Does not disrupt balance of emulsion system 不会干扰乳液体系的平衡Long-lasting efficacy(half-life i
29、s 5-8 months)长效（半衰期5-8个月）Unique balance of oil and water solubilityimportant feature for emulsion systems 突出的水溶性和油溶性对乳液体系非常重要Low total formaldehyde content 总甲醛含量低Evidence for efficacy vs.mycobacteria 对细菌特别有效No skin irritation(no R43)对皮肤刺激性小（不用“贴标签”R43）Easy compatible with common used fungicides(NaPy
30、rion,IPBCs,BBits)容易与抗真菌剂并用Works quite well in pH ranges 7-11 在pH7-11范围内特别有效Concentrate treatment:2,5 3,0%浓缩物加剂量 2.5-3.0%Tankside treatment:not preferred 不推荐用于现场添加Stability problems of CONTRAM ST-1 as sold:solidification at cold temperatures CONTRAM ST-2,CONTRAM ST 1-50 ST-1气温较低时，会凝固，可以使用CONTRAM ST-2
31、，ST-1/50,Product Features,CONTRAM MBOBalanced performance for tankside or concentrate treatment可以用于浓缩物或现场维护Greater oil solubility than competitive materials 油溶性更好Tankside complement to products protected by ST-1 in concentrate(avoid microbe acclimation and resistance)可以用作含有ST-1浓缩物产品使用时的现场维护（避免产生耐药性）
32、High total formaldehyde content for fast activity on existing microbial growth 高甲醛含量可以快速杀死细菌Based on primary amine 基于一级胺Concentrate treatment:2,5 3,0%浓缩物 2.5-3.0%Tankside treatment:0,1 0,2%现场0.1-0.2%Harder incorporation in MWF concentrates additional coupling agents necessary(fatty acids,ethoxylated
33、 or fatty alcohols)需要一些偶合剂以帮助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪醇）,Product Features,CONTRAM 121Unique balance of performance properties 优异的杀菌性能Quick activity for tankside control coupled with good stability in fluid concentrates 在浓缩物中优异的稳定性，同时可以用于现场添加Complement to CONTRAM ST-1 protected fluids alternate tankside
34、 chemistry to avoid microbe acclimation and resistance to one particularbactericide chemical type可以用作含有ST-1浓缩物产品使用时的现场维护替代品，避免某些特定种类的细菌产生抗药性Greater oil solubility than competitive triazines for improved compatibility and stability in metalworking fluid emulsions比三嗪类杀菌剂的油溶性更好，和金属加工乳液有更好的兼容性和稳定性More s
35、table than HHT 比HHT更加稳定Concentrate treatment:2,5 3,0%浓缩物：2.5-3.0%Tankside treatment:0,1 0,2%现场：0.1-0.2%Harder incorporation in MWF concentrates additional coupling agents necessary(fatty acids,ethoxylated or fatty alcohols)需要一些偶合剂以帮助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪醇）,Product Features,CONTRAM OF-GFast-acting p
36、erformance against bacteria for tankside application 快速杀灭细菌，可用于现场添加Complement to CONTRAM ST-1 protected fluids alternate tankside chemistry to avoid microbe acclimation and resistance to one particularbactericide chemical type 可以用作含有ST-1浓缩物产品使用时的现场维护替代品，避免某些特定种类的细菌产生抗药性Amine-free option for applicat
37、ions where this is of concern to formulators and end users(Concentrate and tankside treatment)不含胺，可以用于一些特殊要求的配方或最终客户（浓缩物和现场添加）Near-neutral pH value to avoid dramatic shift in fluid properties when added tankside and to minimize impact on balance of fluid concentrates中性pH值，对浓缩物或现场添加时对pH值得冲击小Particula
38、r efficiency against Mycobacteria 主要针对细菌Concentrate treatment:2,5 3,0%浓缩物：2.5-3.0%Tankside treatment:0,1 0,2%现场添加：0.1-0.2%Harder incorporation in MWF concentrates additional coupling agents necessary(fatty acids,ethoxylated or fatty alcohols)需要一些偶合剂以帮助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪醇）,Product Features,CONTRA
39、M NBF-34Formaldehyde free,based on Isothiazolinon 不含甲醛，基于异噻唑啉基Fast-acting performance against bacteria for tanksideapplication 快速起效，用于现场添加Concentrate treatment:not preferred%不推荐用于浓缩物Tankside treatment:0,1 0,175%现场添加：0.1-0.175%EU:At an application level of max.0.175%in the finished fluid the requirem
40、ents of the 28th ATP directive are fulfilled.The level of CMI/MI is below 15ppm.,Key Physical Properties:Total Formaldehyde Content 总甲醛含量,Performance Profile,Efficacy in MIC-(minimal inhibition concentration in ppm)on Bacteria:,Efficacy in MIC-(minimal inhibition concentration in ppm)on:Fungie,Fungi
41、cides 杀真菌剂 Selection Considerations CONTRAM NFK fungicide and CONTRAM J(IPBCs)fungicide,Characteristics of CONTRAM NFK fungicide,Stabilized solution of sodium pyrithione in water 吡啶硫酮钠的水溶液Water soluble 溶于水Very effective fungicide(yeast and mold)高效杀真菌剂（酵母菌和霉菌）Not considered fast acting due to mode of
42、 action非快速杀灭Sometimes antibacterial 有时对细菌有效Non-irritating and non-sensitizing to humans 对人的皮肤没有影响Has been shown to have no potential for skin sensitization,even at 760 times the normal end use level 即使浓度高于推荐的760倍，也没有发现皮肤过敏,Characteristics of CONTRAM NFK fungicide,Iron can be introduced into metalwor
43、king fluid concentrates through raw materials 通过原料可能带入铁离子Resulting in gray or black formulations 导致工作液颜色变灰或发黑Water-insoluble iron pyrithione may precipitate 非水溶性的吡啶硫酮铁可以析出Can be reversed with additions of iron specific sequestering agents可以通过添加铁离子螯合剂来还原工作液的外观EDTA(Na form best)最好使用EDTA钠盐-NFK fungicid
44、e is stabilized in this form,therefore can be recommended for use in cast iron grinding operations 可以推荐NFK用于铸铁磨削加工,Characteristics,CONTRAM NFKpHProduct pH is alkaline typically 9-11 产品的pH范围 9-11Works well in pH range of most formulations 在广泛pH范围内有效Good thermal stability 热稳定性好Thermal decomposition(po
45、wder)250C 热分解温度（粉末）250CGood stability in formulations which might be shipped or stored in warm climates 在配方中的稳定性好，可以储存在温暖的气候条件,Characteristics of IPBC industrial fungicide,Here on out referred to as IPBCIodo propynyl butyl carbamate 碘代丙炔基丁基氨基甲酸酯 99%powder and various glycol solution blends 99%活性含量的粉
46、末和各种浓度的溶液More oil than water soluble 油溶性Contains 1 atom of iodine per molecule of IPBC 每分子的IPBC含有1个碘原子Very effective,relatively fast acting fungicide 高效，相对快速杀灭真菌,Characteristics,pHNo inherent pH Prefers neutral pH formulations 更倾向用于中性pH配方Chemical instability when pH 9.0 pH9.0可能会导致不稳定Moderate thermal
47、 stability(powder)粉末IPBC的热稳定性中等Temperature of decomposition 150C 热分解温度150CMelting point 65C 熔点65CNot well suited for storage in formulations which might be shipped or stored in warm climates 不太适合用于海运到或储存于热带地区的产品中Care must be taken when making MWF concentrates which require heat 对需要加热调配MWF浓缩物时，必须当心So
48、luble Oil and Semi-synthetic blends 可溶油和半合成液When possible allow blend to cool 45C 冷却到45C后再加入When possible add the product at the end of the mfg.process 在调配工序的最后阶段加入,Biocide Characteristics,The mode of action of these two products is quite different 这两种产品的作用机理有所区别IPBC has not been studied in detail,b
49、ut in simple terms is an iodine delivery system IPBC的作用机理简单理解为引入碘NFK disrupts the cell proton mode of force,cells lose the ability to store energy and carry out vital functions(cells starve to death)NFK可以破坏细胞质，导致细胞丧失储备能量和活力的功能（最终会被饿死）Due to this mechanism an advantage is that NFK will not give rise
50、to acquired resistance 基于上述机理，不会产生抗药性This also explains why its not a very fast acting anti-microbial也就可以解释为什么不是快速杀灭真菌剂,Recommended Use Levels推荐剂量,NFK MWF concentrates 浓缩物0.50-1.0%0.50-1.0%,product as soldPost Treatment 现场处理 500-1000ppm500-1000 ppm,product as sold IPBCMWF concentrates 浓缩物0.15-0.5%（相
