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1、华东理工有机化学第11章作业参考答案11-1 2）邻氨基苯甲酸甲酯 4）邻苯二甲酰亚胺 6）反-2-甲基环己基甲酸 8）2-环己酮基甲酸甲酯 10）甲酸苄酯 11-2 OCH2=CCOCH3(3) (5)CH3OCH3C (7) (9)OC2H5COOOCCH3COOHOCH3HCNCH3CH2CH2n OH(11)11-8 (1) HCOOCH3 CH3CO2CH3 CH3CO2C2H5 CH3CO2CH(CH3)2 CH3CO2C(CH3)3 , (2)O2NCO2CH3 ClCO2CH3 CO2CH3 CH3OCO2CH3 11-10 OOO(1)ClCH2COHCH3COHCH3CH2
2、OHCH3CNH2(2)O2NOCOHOCOHO2NOHCH2OHOCOHOCOHCH3OOCOH(3)(4) 草酸丙二酸甲酸乙酸苯酚 11-11 (2)CH3Cl2光CH2ClCN-CH2CNH3O+OCH2COHOO1)NaOC2H5(4)2CH3CH2CO2CH2CH3CH3CH2CHCHCOCH2CH32)H+CH3NaBH4OHOCH3CH2CHCHCOCH2CH3CH3O(6)CH3OH/H+CO2HNaBH4HOCO2CH3(8) CH3CH2CH2COOHCl2/PCH3CH2CHCOOHClCN-H2O/H+CH3CH2CHCOOHCOOH11-12 OO1) NaOC2H5
3、(1)CH3C(CH2)3COC2H5O H+OOCH2CCH2CH2CH2COC2H5OOC2H5-C2H5OHOO(2) -环己酮甲酸乙酯含有活泼亚甲基，在碱性条件下与,-不饱和酮，先发生1,4加成，再发生分子内的羟醛缩合，生成环状,-不饱和酮。 OCO2C2H5ONaOC2H5CO2C2H5OCOOC2H5NaOC2H5OO-O-NaOC2H5COOC2H5OO-COOC2H5OOCOOC2H5_H2OOCOOC2H5CHOH25_ CHO-25O(3) -卤代酯在强碱作用下与酯、酮反应生成,-环氧羧酸酯。 OOClCH2COEtOt-BuOKOClCHCOEtCl CHCOOEtO C
4、HCOOEt11-13 (1)CH3CH2OHOCH3COOHOC2H5OHH+CH3CO2C2H5Br2/PZn/醚BrZnCH2COOC2H5H3+OCH2COOHOHReformastsky反应(3) 分析CH3OCCH3OOCH3CCH2CH2CH2CH2CCH3OOCH3CCH2COC2H5+BrCH2CH2Br合成CH3CH2OHNaOC2H5 BrCH2CH2BrOC2H5OHH+稀OH-1.H32.+OCH3CO2C2H5NaOC2H5 C2H5OHOOCH3CCH2COC2H5OH-,CO2OOCH3CCH2CH2CH2CH2CCH3CH3OCCH3COOC2H5CHCH3C
5、OOC2H5OCOOC2H5OCO2C2H5CO2C2H5COOC2H5O(5) 分析：O己二酸COOC2H5OOCH2CHCCH3NaOC2H5合成： CO2HCO2HC2H5OHH+CO2C2H5CO2C2H5NaOC2H5C2H5OHCOOC2H5OOH-COOC2H5OCOOC2H5CH3CHPPh3OCHCH311-14 A.CH3CH2COOCH2CH3；B. CH3CH2COCH(CH3)COOCH2CH3； C. CH3CH2COC(C2H5)(CH3)COOCH2CH3； D. CH3CH2COCH(CH3) CH2CH3。 O O11-15 BrCH2CH2CH2Br，NCCH2CH2CH2CN，HO2CCH2CH2CO2H， O
