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1、有机化学完成反应式上答案有机化学练习题答案 Cl1.CH2CH3Cl2500600CoCHCH3CH3CH=CHCH2Br2.CH3CH=CHCH3NBS, (C6H5COO)2CCl4, ROOR3.CH3+HBrCH3BrCH34.CH3HC=CCH3H+Br2HBrBrHCH3+BrHCH3HBrCH35.CH3CH3CO3HNa2CO3CH3( )O( + )H+, H2OCH3HO( )OHH( + )6.H2C=CHCH2CH2CH=CH2Hg(OAc)2H2ONaBH4OHOHCH3CHCH2CH2CHCH3Cl7.CH3CH3+HOClCH3ClOHCH3CH3CH3( + )
2、 OH+8.HCl重排+Cl-Cl( )Cl2ClClCH3CHCHCH2CH=CHCCl39.CH3CH=CHCH2CH=CHCCl3 1 CH310.CH312B2H6H2O2/OH-H( )OHH( + )冷KMnO4OH-OHOH11.COOH12.+COOH不反应OO( )NHOO13.O+NHOCH314.+CHOCH3CHO( )Br15.CH3BrHCH2CH3CH3ZnCH3CH3CH2CH3CCH16.CH3CH2CH2CCCH3Na/NH3(l)HCH3CH2CH2CCCH3H17. CH2=CHCH2CH2CCHH21molCH3CH2CH2CH2CCH18. CH2=
3、CHCCHH21molCH2=CHCH=CH2OH19.CH2=CHCHCCCH3OHPd/BaSO4喹啉CH2=CHCHHCCCH3H 2 Cl20.CH3COOClAlCl3CH3COOCl21.+AlCl3NO222.+CH3COClAlCl3( )不反应9 CH3CHO23.CH2=CCH=CH2+CH2=CHCHO( )CH3NaBH4CH2OH( )CH3NO224.Br2FeNO2BrO25.CH3+CH3CH2CH2CClAlCl3OCH3CCH2CH2CH3ZnHgHClCH3CH2CH2CH2CH3CH326.CH3CCH2OHCH3ClZnCl2/HClCH3CCH2CH
4、3CH327.ClCH2CH2CH2CH2OHNaOHO28.CH3CH=CHCH2CH2OHH+CH3CH=CHCH=CH2CH329.ClCH3NaOHC2H5OHCH3CH3 3 CH3H30.HBrC6H5OHC2H5ONaHHCH3OHOC2H5C6H5+HOC2H5OCH3HHC6H5Br31.BrKOH/C2H5OHHO32.DHCCH2CH3TsCl吡啶NaI丙酮TsODHCCH2CH3,CH3CH2CIDHCH333.DHCBrNaI丙酮ICDCH3HCH2CH2CH334.CH3CCH3Br+CH3CCNa(CH3)2C=CHCH2CH3CH335.HC2H5BrHCH3N
5、aI丙酮IC2H5CH3HHCH3ClClCl36.O2NNO2NaOCH3CH3OHCH3OO2NNO2OH37.OHH+O 4 38.CH3OHH2SO4H2O+orOH2+OO39.O1 O32 Zn/H2OOC6H540.H3CCH3OCH3HCH3OHH+C6H5HOOCH3HCH3及其对映体H41.HOCH3H1 CH3Li H+O23HOCH3CH3CH2HHOCH3HCH2CH3O42.CHCH=CHCH3C2H5OHCH3CHCH=CHCH2CH3O43.HOOHH+OOO44.CH3CH2CH2NH2+NCH2CH2CHH2/Pt3NHCH2CH2CH3O45.CH3CCH
6、(CH3)2LDA。THF, -78 COLiCH2=CCH2CH3C6H5CHOH2OOCH=CHCCH2CH3OH46.CH3C6H5COCH1 C2H5MgBr+ 2H3OC2H5C2H5CH3HOHCH3HPhHOC6H5HHC2H5CH3HPhH 5 OOO47.CF3CO3HCH348.OOCH3H+H2OOHOCH3OH2+H+OOCH3OHH2OOOHOO49.OH3+OHO+OHHOCH3Ph3P=CHOCH3CH3CH2=CHCCH2CH=CHOCH3CH3CH350.CH3C=CHCH2OCH=CH2CH2=CHCCH2CHOCH3H3O+CH3CH2=CHCCH2CH2
7、CHOCH3，第二步Wittig反应，第三步乙烯基醚水解生成醛） O51.1 CH3Li+ 2H3OHOCH3O52.(CH3)2CuLiCH3O53.H2NiOHN54.CH3CO+NH2OHCCH3H+NHCOCH3CH2CH2CH3O55.CHO+CH3CH2CC(CH3)3C2H5OH/H2ONaOHCH3CH=CCC(CH3)3O 6 56.CHOKMnO4COOHO+COOHH58.OHCrO3,H2SO4H2O,CH3COCH3CrO3,H2SO4H2O57.HCCCH2OHHCCCHOOOC6H5CC6H5OOHC6H559.OCHC6H5(CHN) .CrO5523CH2Cl
8、2O60.HOCH2CH2CH2CH2CCH3+CH3CH2MgBrCH3CH3O+BrMgOCH2CH2CH2CH2CCH3O61.CH3CCH2CH2CH2COOH+CH3MgBrOCH3CCH2CH2CH2COOMgBr+CH462.HCCCH2CH2CH2CHO+MgBr+BrMgCCCH2CH2CH2CHO反应） OH63.CH3CHOCCH3I2, NaOHNaOOCCOONa+CHI3CH3SO3H苯，64.O+HNNO65.C6H5CC6H5+NaHSO3( )饱和不反应OOH66.CH3CH=CHCHCH3(CH3)3CO3AlCH3COCH3,CH3CH=CHCCH3 7
9、O67.2CH3CCH3Mg/C6H6H2OCH3CH3CH3COHCOHCH3Al2O3CH2=CC=CH2CH3CH3O68.MgHg/THFTiCl4CH3CH3CH3COHCOHCH3H+CH3OCH3CCH3CCH3CH3CH3CCH3ZnHgHClCH3CCH2CH3CH3H69.NOHH+110CoHNOCHO70.CHONaOHCHOHOOCH(CH2)5 C CH371.OHN H( N 2 2 )NaOH二缩乙二醇OCH(CH2)5 CH2 CH3OH/H2O+CH3(CH2)6CHO( )OCHO72.C2H5CHONaOHH+/H2OCOOHC2H5CH2OHH2SO4
10、C2H5OO73.CH3CH2CCH3+Cl2( m1ol)H2O, HOAcOCH3CHCCH3ClO74.(CH3)3CCCH3Br2, NaOH过量O(CH3)3CCCOONa+CHBr3） CH375.OBr2, NaOHCH32molBrOBrCH=CHCHOO2N76.O2NCHO+CH3CHONaOH 8 OHO+CH3CCH3干HCl77.OHOO） O78.+CH3CH2CCNaHOCCCH2CH3O79.CH3CCH(CH3)2LDATHF, -78OLiOCH3CH2CHOH2O( )CH2=CCH2CH3CH3CH2CH=CHCCH2CH380.OHI( )过量ICH2CH2CH2I81.CHI )( 3 (CH3)2CHOCH3(CH3)2CHONa浓HI1mol )(CH 3 ) )+( CH3I2CHOHO82.CH3CH3CH3HBrHOCH2CH2CCH3Br83.OCH=PPh3+CHOCH=CHOOH84.OHCH3COOHH+OHOCOCH3O2N85.O2NOCH3HI1molOH+CH3I 9
