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1、烃及其衍生物之间的相互转化关系烃及其衍生物之间的相互转化关系 高聚酯(40)CH3(14)(37)CH3O2NCOOHNO2OH(16)(17)NO2CH2CH2CH2CH2n(6)(34)CH2OHCH2OH(36)(38)CHOCHO(39)COOHCOOHBr(11)(15)Br(3)Br(35)CaC2(10)(7)(8)六元环状酯ONaCH3CH3(2)CH2CH2CHCH(9)(13)(12)(1)(4)(33)(5)(20)CH2CHClCH2CHClCu2O(25)(26)(24)NO2(18)nOHBrCH3COOH(30)AgCH3CH2Br(32)(22)BrCH3CH2
2、OH(21)(19)(23)(27)CH3CHO(28)(29)Br(31)CH3CH2OCH2CH3CH3CH2ONaCH3COOCH2CH3CH3COONa第 1 页 共 4 页 第 2 页 共 4 页 CH光照3CH3+Br2 CH3CH2Br+HBr CH催化剂2CH2+H2CH3CH3 CH2CH2+Br2CH2BrCH2Br CH2CH2+HBrCH3CH2Br CH浓H2CH2+H2O2SO4CH3CH2OH n CH催化剂2CH2 CH2CH2nCHCH+H催化剂2CH2CH2 CHCH+HCl催化剂CH2CHCl nCH2CH催化剂CH2CHClCln CaC2+2H2OCH
3、CH+Ca(OH)2 + Br催化剂2Br + HBr + HONO浓H22SO4NO2 + +3H催化剂2 H2O 第 3 页 共 4 页CH3CH3+ 3HONO浓HSOO2NNO2224+3H2O NO2CH3COOH酸性KMnO4或酸性K2Cr2O72OH+2Na2ONa+H2 OH+NaOHONa+H2O OH+Na2CO3ONa+NaHCO3 ONa+HClOH+NaCl ONa+CO2+H2OOH+NaHCO3 OHOHBrBr+3Br2+3HBr Br2CH3CH2OH+2Na2CH3CH2ONa+H2 CH浓H2SO43CH2OH1700CCH2CH2+H2O C浓H2SO4
4、2H5OH+HOC2H51400CC2H5OC2H5+H2O CH3CH2OH+HBr CH3CH2Br+H2O 2CH催化剂3CH2OH+O22CH3CHO+2H2O CH3CH2OH+CuO CH3CHO+Cu+H2O 2CH催化剂3CHO+O22CH3COOH CH3CHO+2Ag(NH3)2OH CH3COONH4+2Ag+3NH3+H2O CH3CHO+2Cu(OH)2 CH3COOH+Cu2O+2H2O CH催化剂3CHO+H2CH3CH2OH CHH浓H2SO43COOH+HOC25CH3COOC2H5+H2O CHO稀H2SO43COOC2H5+H2CH3COOH+C2H5OH
5、 2CH3COOH+2Na2CH3COONa+H2 2CH3COOH+Na2O2CH3COONa+H2O CH3COOH+NaOHCH3COONa+H2O 2CH3COOH+Na2CO32CH3COONa+H2O+CO2 CH3COOH+NaHCO3CH3COONa+H2O+CO2 第 4 页 共 4 页CH3COOC2H5+NaOH CH3COONa+C2H5OH CH水3CH2Br+NaOHCH3CH2OH+NaBr CH乙醇3CH2Br+NaOHCH2CH2+NaBr+H2O CH2Br水CH2OHCH2Br+ 2NaOHCH2OH+2NaBr CH乙醇2BrCH2Br+2NaOHCHCH+2NaBr+2H2O CH2OH催化剂CHOCH2OH+O2CHO+2H2O CHOCHO+O催化剂COOHCHOOH2COOHCHO+2H催化剂CH22CH2OHCOOHCHOO2OH浓H2SOCCH2COOH+4CH2OHCCH+2H2O OO2nCOOHOOCOOH+nCH2OH浓H2SO4CH2OHHOCCOCH2CH2OHn+(2n1)H2O
