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1、豆丁网：BRITISH STANDARDAdhesives Determination of ash and sulfated ashThe European Standard EN 1246:1998 has the status of aBritish StandardICS 83.180| BS EN1246:1998|第 5 页 共 13 页豆丁网：Licensed Copy: sheffieldun sheffieldun, na, Sat Oct 28 09:00:35 GMT+00:00 2006, Uncontrolled Copy, (c) BSI|NO COPYING WI
2、THOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBS EN 1246:1998National forewordThis British Standard is the English language version of EN 1246:1998.The UK participation in its preparation was entrusted to Technical CommitteeSTI/52, Adhesives, which has the responsibility to: aid enquirers
3、 to understand the text; present to the responsible European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK.A list of organizations represented on this c
4、ommittee can be obtained on request to its secretary.Cross-referencesThe British Standards which implement international or European publications referred to in this document may be found in the BSI Standards Catalogue under the section entitled International Standards Correspondence Index, or by us
5、ing theFind facility of the BSI Standards Electronic Catalogue.A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application.Compliance with a British Standard does not of itself confer immunity fro
6、m legal obligations.Summary of pagesThis document comprises a front cover, an inside front cover, the EN title page, pages 2 to 4, an inside back cover and a back cover.Licensed Copy: sheffieldun sheffieldun, na, Sat Oct 28 09:00:35 GMT+00:00 2006, Uncontrolled Copy, (c) BSIAmd. No.DateText affected
7、This British Standard, having been prepared under the direction of the Sector Board for Materials and Chemicals, was published under the authority of the Standards Board and comes into effect on 15 July 1998BSI 1998ISBN 0 580 29636 9Amendments issued since publicationEUROPEAN STANDARDEN 1246NORME EU
8、ROPE ENNEEUROPA ISCHE NORMFebruary 1998ICS 83.180Descriptors: Adhesives, chemical analysis, ash determination, analysis methodsEnglish versionAdhesives Determination of ash and sulfated ashAdhe sifs De termination du taux de cendres total et du taux de cendres sulfate esKlebstoffe Bestimmung der Asc
9、hegehaltes und des Sulfat-AschegehaltesLicensed Copy: sheffieldun sheffieldun, na, Sat Oct 28 09:00:35 GMT+00:00 2006, Uncontrolled Copy, (c) BSIThis European Standard was approved by CEN on 24 January 1998.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the
10、 conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in t
11、hree official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions.CEN members are the national standards bodies of A
12、ustria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom.CENEuropean Committee for Standardization Comite Europe en de Normalisation Europa isches Komitee fu r Normung
13、Central Secretariat: rue de Stassart 36, B-1050 Brussels1998 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN nationalMembers.Ref. No. EN 1246:1998 EPage EN 1246:1998Licensed Copy: sheffieldun sheffieldun, na, Sat Oct 28 09:00:35 GMT+00:00 2006, Uncontrolled Cop
14、y, (c) BSIForewordThis European Standard has been prepared by Technical Committee CEN/TC 193, Adhesives, the secretariat of which is held by AENOR.This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by A
15、ugust 1998, and conflicting national standards shall be withdrawn at the latest by August 1998.According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European standard: Austria, Belgium, Czech Republic, Denmark,
16、Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the United Kingdom.BSI 1998Page 3EN 1246:19981 ScopeThis European Standard specifies two conventional methods for the determination of ash and sulfated ash content of
17、a synthetic or natural adhesive.2 Normative referencesThis European Standard incorporates, by dated or undated reference, provisions from other publications. These normative references are cited at the appropriate places in the text and the publications are listed hereafter. For dated references, su
18、bsequent amendments to or revisions of any of these publications apply to this European Standard onlywhen incorporated in it by amendment or revision. For undated references the latest edition of the publication referred to applies.EN 827, Adhesives Determination of conventional solids content and c
19、onstant mass solids content.EN 923, Adhesives Terms and definitions. EN 1066, Adhesive Sampling.EN 1067, Adhesives Examination and preparation of samples for testing.ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeata
20、bility and reproducibility of a standard measurement method.3 DefinitionsFor the purposes of this standard, the definitions given in EN 923 apply.4 Principle4.1 Method A: determination of the percentage of ashPreliminary drying and combustion of the test sample and ashing in a muffle furnace at a pr
21、edetermined temperature to constant mass.4.2 Method B: determination of the percentage of ash as sulfatesPreliminary combustion of the test sample, treatmentof the residue with sulfuric acid, heating, neutralization of excess acid by the addition of ammonium carbonate and heating. Then ashing in a m
22、uffle furnace at a predetermined temperature to constant mass.5 SafetyPersons using this standard shall be familiar with normal laboratory practice.This standard does not purport to address all safety problems, if any, associated with its use.It is the responsibility of the user to establish appropr
23、iate safety and health practices and to ensure compliance with any European and national regulatory conditions.6 Reagents (used only for sulfated ash)6.1 Sulfuric acid, pure, r 1,84 g/ml.6.2 Ammonium carbonate, anhydrous, powdered, analytical reagent grade.7 Apparatus7.1 Crucibles, of silica, porcel
24、ain or platinum, 45 mm to 75 mm diameter and a depth not less than thelength of the diameter. Deep crucibles are particulary recommended, especially for the determination of sulfated ash.7.2 Bunsen burner or equivalent apparatus.7.3 Muffle furnace, gas or electric, controlled at(850 20) 8C.7.4 Oven,
25、 adjustable between 80 8C and 135 8C.7.5 Analytical balance, accurate to 0,0001 g.7.6 Desiccator, containing conventional desiccant.7.7 Pipette.8 SamplingA significant sample of the adhesive shall be taken in accordance with EN 1066 and prepared for testing in accordance with EN 1067.9 ProcedureCarr
26、y out the following procedure in duplicate. Calculate the mass m1 in grams of ash from thedifference in the weighings.Calculate the mass ms1 in grams of sulfated ash from the difference in the weighings.9.1 Method A: determination of the percentage of ash9.1.1 Heat the crucible (see 7.1) at (850 20)
27、 8C to constant mass and cool in the desiccator (see 7.6). Weigh the crucible to the nearest 0,0005 g and add 2 g to 3 g of adhesive. Reweigh the crucible and its contents to the nearest 0,0005 g and calculate themass m0 of the adhesive used.9.1.2 Dry in the oven (see 7.4) under the same conditions
28、as those used to measure the conventional solids content in accordance with EN 827 for the adhesive involved.Solid adhesives do not require this operation.9.1.3 Gently heat the crucible with the Bunsen burner (see 7.2), or equivalent apparatus, until all volatile matter and any other products of com
29、bustion are completely volatized. This is indicated by the disappearance of the black colour from the insidewalls of the crucible.The ashing shall be carried out slowly so that the volatiles do not carry off particles of ash.Licensed Copy: sheffieldun sheffieldun, na, Sat Oct 28 09:00:35 GMT+00:00 2
30、006, Uncontrolled Copy, (c) BSIBSI 1998Page EN 1246:1998BSI 1998Licensed Copy: sheffieldun sheffieldun, na, Sat Oct 28 09:00:35 GMT+00:00 2006, Uncontrolled Copy, (c) BSI9.1.4 Place the crucible in the muffle furnace(see 7.3) controlled at (850 20) 8C and heat for10 min.After cooling in the desiccat
31、or, weigh the crucible to the nearest 0,0005 g.Heat again for 10 min, re-cool in the desiccator and reweigh.Repeat these operations until constant mass is obtained, i.e. until two successive weighings do not differ by more than 0,0005 g.9.2 Method B: determination of the percentage of sulfated ash9.
32、2.1 Heat the crucible (see 7.1) at (850 20) 8C to constant mass and cool in the desiccator (see 7.6). Weigh the crucible to the nearest 0,0005 g and add 2 g to 3 g of adhesive. Reweigh the crucible and its contents to the nearest 0,0005 g and calculate the mass m0 of the adhesive used.9.2.2 Dry in t
33、he oven (see 7.4) under the same conditions as those used to measure the conventional solids content in accordance with EN 827 for the adhesive involved.Solid adhesives do not require this operation.9.2.3 Gently heat the crucible with the Bunsen burner (see 7.2) or equivalent apparatus until all vol
34、atile matter and any other products of combustion are completely volatized. This stage is indicated by the disappearance of the black colour from the insidewalls of the crucible.The ashing shall be carried out slowly so that the volatiles do not carry off particles of ash.9.2.4 Allow the crucible an
35、d contents to cool.By means of the pipette (see 7.7) add to the crucible successive small quantities of sulfuric acid (see 6.1), warming carefully with the bunsen burner (see 7.2) until the reaction is completed.Then, add ammonium carbonate (see 6.2) to neutralize excess acid, warming until the emis
36、sion of white fumes ceases.9.2.5 Place the crucible in the muffle furnace(see 7.3) controlled at (850 20) 8C and heat for10 min.After cooling in the desiccator, weigh the crucible to the nearest 0,0005 g.Heat again for 10 min, re-cool in the desiccator and reweigh.Repeat these operations until const
37、ant mass is obtained, i.e. until two successive weighings do not differ by more than 0,0005 g.10 Expression of resultsFor each determination calculate the percentage of ash or sulfated ash to two decimal places by means of the formulae:ash % = m1 3 100m0sulfated ash % = ms1 3 100m0where:m0 is the ma
38、ss, in grams, of adhesive used;m1 is the mass, in grams, of ash;ms1 is the mass, in grams, of sulfated ash.Calculate the mean to the nearest 0,0005 grams of the two values finally obtained.In the test report include the mean as the value of the percentage of ash or sulfated ash.11 Precisiona) Repeat
39、ability (in accordance with ISO 5725-2):0,10 %b) Reproducibility (in accordance with ISO 5725-2):0,20 %12 Test reportThe test report shall include:a) a reference to this draft European Standard;b) the type and designation of the adhesive tested;c) the result of the test expressed in accordance with
40、clause 10;d) any circumstances which may have affected the result;e) date of test.blankLicensed Copy: sheffieldun sheffieldun, na, Sat Oct 28 09:00:35 GMT+00:00 2006, Uncontrolled Copy, (c) BSIBSI389 Chiswick High RoadLondonW4 4AL| BSI British Standards Institution| BSI is the independent national b
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