液体中激光烧蚀法制备纳米材料.ppt

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1、,Group members:Ou Qian,Chao Zhang,Dan Jia,Yanping Su,Lulu Wen,Gangfeng Wei,Yongkui Wang,Dongfang Wang,Xiangyang Song,Wen Wang,Haiying Zheng.,Nanomaterials Generated by Laser Ablation in Liquids,Basic mechanism of LAL(laser ablation in liquids),Sketch of the main stages of LAL,Phys.Chem.Chem.Phys.,20

2、13,15,3027-3046,Basic mechanism of LAL,Sketch of the plasma plume formed by laser ablation of a metal target.*Denotes excited and/or ionized states,Phys.Chem.Chem.Phys.,2009,11,38053821,Basic mechanism of LAL,FeO Nanoparticles by LAL,Adv.Funct.Mater.2012,22,13331353,Nanoparticles Derived from LAL me

3、thod,High activity and reactivity,LAL-inducedNPs,Stable and surface passivated,A(assemble or growth)A+B=C New compounds=AB Composites,Activity and Reactivity,C,Examples,1.LAL-based to fabricate carbon-encapsulated metal carbides2.LAL-based synthesis of ternary oxides3.LAL-based complex oxidenoble me

4、tal nanocomposites,pulse laser,acetone,target,Tantalum target,1.LAL-based to fabricate carbon-encapsulated metal carbides,TaCC NPs,Carbon,2013,55,108115,NbCC,MoxCC,Co3CC,Mo in ethonal,Nb in ethonal,Co in acetone,More products can be synthesized,the formation process of carbon-encapsulated metal carb

5、ides,2.LAL-based synthesis of ternary oxides,J.Mater.Chem.,2012,22,1721017214,Design for ternary oxides based on A+B=C,various ternary oxides,Morphology,structure and size can be modified,Reaction temperatureReaction timepH value,3.LAL-based complex oxidenoble metal nanocomposites,Adv.Mater.2013,25,20402044,Brief Summary,LAL-generated NMs present unique activity,beneficial for obtaining new properties and new structuresLAL-generated NMs display unique reactivitycan be used as precursors for preparing new materialsLaser-generated NMs show unique applicationin catalyst,biosensor etc.,THANKS,

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