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1、PTS中普检测Product Technology Service,化学品检测项目及测试方法,证书编号：2009111205Z,CPSC实验室编号：1142,认可检测实验室,The collection of the requirements on Environmental protection and harmful substances controlling.环保和有害物质控制要求汇总,Environmental Protection 环保-the material recovery and collection and control the harmful substances c
2、ontaining 材料的再生和回收,以及有害物质的控制。-scope:check the finished products 范围：针对整机产品的控制,Chemical harmful substances 化学有害物质-the substances harm to human directly 对人体健康有害-scope:check component and material more 范围：针对材料和元器件的控制,Directive on:RoHS/WEEE(EU)-ELV(EU)Packaging(EU)-Battery(EU)EuP,IPP,EPP(EU)Emission(exha
3、ust)-ODCs(groupGroup Group Group Group Group Group Group)halogenated plastics or polymersetc,REACH(EU)NP-Penta/Oct-BDE,Laws on-PAHs-Phthalates-Cadmium directive-asbestos-1935/2004/EC,food contacted products-the substances in 76/769/EC,such as benzene,hexachlorobenzene,toluene.Xylene,Cyanides,phenol(
4、monomer),Plasic oriented materials(acrylonitrile,VCM,Epichlorohydrine,styrene),Organic tin compounds,azo dyes,PCBs,PCTs,PBBs,PBDEs,TBBP-A-bis,asbestos,Sb2O3formaldehyde,etc-relavant product chemical requirement,-VOCs,such as EN71-3/9/10/11.etc,什么是RoHS 欧盟议会和欧盟理事会于2003年1月通过了RoHS指令，全称是The Restriction o
5、f the use of certain Hazardous substances in Electronical and Electronic Equipment,即在电子电气设备中限制使用某些有害物质指令，也称2002/95/EC指令，2005年欧盟又以2005/618/EC决议的形式对2002/95/EC进行了补充，明确规定了六种有害物质的最大限量值。,一、RoHS,1.1指令常见问题,欧盟为何要颁布RoHS指令？一是设立技术壁垒，提高产品准入门槛，二是加强环境保护，确保可持续发展。,有害物质的限值是多少？铅（Pb）、汞(Hg)、六价铬(Cr6+)、多溴联苯(PBB)、多溴二苯醚(PBD
6、E)的最大允许含量为0.1%(1000ppm)，镉(cd)为0.01%(100ppm),Designed to operate at a maximum voltage of 1,000 V a.c.or 1,500 V d.c;Falling within 8 categories of RoHS;包括:设计最大工作电压不超过 1000 V a.c 或 1500 V d.c，通过电流、电磁场、发电机、变压器工作的设备或测量这种电流的设备；适用于8类产品;,1.2 范围的确认RoHS,Large Household Appliances 大型家用电器Small Household Applia
7、nces 小型家用电器IT and Telecommunications Equipment 信息与通讯设备4.Consumer Equipment 消费性设备5.Lighting Equipment 照明设备Electrical and Electronic Tools 电子与电气工具7.Toys,Leisure and Sports Equipment 玩具,休闲娱乐设备与运动器材8 Medical Devices(not implanted and infected devices)(after 2008)医疗装置(不包含灌输与被污染的装置)(2008之后)9 Monitoring an
8、d Control Instruments(after 2008)监测与控制仪表(2008之后)10.Automatic Dispenser自动售货机,Legislation 法律限制-EU 欧盟:76/769/EC,89/677/EC:no used,禁止使用 94/62/EC,Pb+Cd+Hg+Cr(VI)100ppm RoHS(2002/95/EC),1000ppm 2006/66/EC for Battery 电池指令:40ppm ELV(2000/53/EC,and related amended version:2002/525/EC,2005/63/EC,2005/438/EC,
9、2005/673/EC)报废车辆指令:0.1%-China 中国:China RoHS(management methods on the prevention and control of pollution caused by electronic information projects.)电子信息产品污染防治管理办法 1000ppm-US 美国:California Prop.65 for cable 加州65对于电缆要求:300ppm 16CFR1303.3 for coating 美国消费产品安全委员会对油漆层要求:600ppm-Japan 日本:Law for the Promo
10、tion of Effective Utilization of Resources 资源有效利用促进法 Green Purchasing law 绿色采购法（GPL）,1.3 有害物质简介RoHS,1.3.1 Lead Directive 铅-相关指令,1.3.2 Cadmium-Directive 镉-相关指令,Legislation 法律限制-Japan 日本:Law for the Promotion of Effective Utilization of Resources 资源有效利用促进法 Green Purchasing law 绿色采购法（GPL）-EU 欧盟:76/769/
11、EC,91/338/EC:0.01%94/62/EC,Pb+Cd+Hg+Cr(VI)100ppm RoHS(2002/95/EC),100ppm 2006/66/EC for Battery 电池指令:20ppm ELV(2000/53/EC,and related amended version:2002/525/EC,2005/63/EC,2005/438/EC,2005/673/EC)报废车辆指令:0.01%-SWEDISH 瑞典 1.SWEDISH ORDINANCE SFS 1998:944 FOR TOTAL CADMIUM CONTENT 2.SWEDISH ORDINANCE
12、SFS1985:839 FOR TOTAL CADMIUM CONTENT-NETHERLANDS 荷兰 1.Netherlands Law Gazette 1990 No.538 and Amendments in 1993 No.39 and No.442,and in 1994 No.782(Cadmium Decree,Law on Environmental Dangerous Substances)2.NETHERLANDS CADMIUM DECREE WMS 1999 NO.149 FOR TOTAL CADMIUM CONTENT,-UK 英国 UK ENVIRONMENTA
13、L PROTECTION(CONTROLS ON INJURIOUS SUBSTANCES)(NO.2)REGULATIONS 1993 NO.1643 FOR TOTAL CADMIUM CONTENT-SWITZERLAND 瑞士 SWITZERLAND ORDINANCE RELATING TO ENVIROMENTALLY HAZARDOUS SUBSTANCE(JUNE 9,1986)FOR TOTAL LEAD AND CADMIUM CONTENTS TEST SWITZERLAND2=SWITZERLAND NOTIFICATION ON THE MATERIALS REGUL
14、ATION(STOV)NO.22(1991)FOR TOTAL CADMIUM CONTENT TEST-GERMAN 德国 German chemical prohibition ordinance paragraph 18 total cadmium content-China 中国:China RoHS(management methods on the prevention and control of pollution caused by electronic information projects.)电子信息产品污染防治管理办法 Limit 限量指标:100ppm,-Direc
15、tive 镉-相关指令,Chrome(VI)六价铬 Legislation 法律限制-EU 欧盟:76/769/EC:no used 不能使用 94/62/EC,Pb+Cd+Hg+Cr(VI)100ppm RoHS(2002/95/EC),1000ppm ELV(2000/53/EC,and related amended version:2002/525/EC,2005/63/EC,2005/438/EC,2005/673/EC)报废车辆指令:0.1%1999/179/EC,2002/231/EC for shoes:10ppm-EN420 for leather gloves:2ppm-C
16、hina 中国:China RoHS(management methods on the prevention and control of pollution caused by electronic information projects.)电子信息产品污染防治管理办法-Japan 日本:Law for the Promotion of Effective Utilization of Resources 资源有效利用促进法 Limit 限量指标 1000ppm,1.3.3 Chromium(VI)-Directive 六价铬-相关指令,1.3.4 Mercury-Directive 汞
17、-相关指令,Legislation 法律限制-EU 欧盟:76/769/EC,89/677/EC:no used 不能使用 94/62/EC,Pb+Cd+Hg+Cr(VI)100ppm RoHS(2002/95/EC),1000ppm 2006/66/EC(91/157/EC,98/101/EC)for Battery 电池指令:5ppm,and 2%for button cells(纽扣电池2%)ELV(2000/53/EC,and related amended version:2002/525/EC,2005/63/EC,2005/438/EC,2005/673/EC)报废车辆指令:0.
18、1%-China 中国:China RoHS(management methods on the prevention and control of pollution caused by electronic information projects.)电子信息产品污染防治管理办法 Limit 限量指标:1000ppm-US 美国:Battery law 电池法规:25mg-Japan 日本:Law for the Promotion of Effective Utilization of Resources 资源有效利用促进法 Green Purchasing law 绿色采购法（GPL）
19、,1.3.5 PBBs&PBDEs-Directive多溴联苯和多溴联苯醚-相关指令,Legislation 法律限制-EU 欧盟:76/769/EC,83/264/EC:no used 不能使用 2003/11/EC,Penta-BDE and Octa-BDE no used,五溴联苯醚和八溴联苯醚,禁止使用.RoHS(2002/95/EC),1000ppm ELV(2000/53/EC,and related amended version:2002/525/EC,-China 中国:China RoHS(management methods on the prevention and
20、control of pollution caused by electronic information projects.)电子信息产品污染防治管理办法 1000ppm-US 美国:Federal 联邦政府:HL4076:Penta-/Octa-/Deca-BDE banned from Oct.,1,2005 Maine 缅因州:LD1790:PBDE banned Illinois伊利诺斯州:HB2572/SB424:Penta-/Octa-BDE banned from 2006,and Deca-BDE banned from 2008 California 加州:AB302/25
21、87/263:PBB/PBDE banned from Jan.1,2006 Hawaii夏威夷:HB2013:PBDE banned Cincinnati辛辛那提:SB785:PBDE banned Minnesota 明尼苏达州:HB83:PBDE banned Michigan 密歇根州:HB4406,SB1548:PBDE banned,8.Deca-BDE 十溴联苯醚 Swedish government has decided to restrict decabromodiphenyl ether(Deca-BDE)in textiles,furniture and cables
22、as of January 1,2007,which is in breach of EU law.瑞典政府已经决定限制十溴联苯醚在纺织品、家具和电源线中的使用，从2007年1月1日开始，它与欧盟指令相违背。,Some questions need to be confirmed on ROHS关于RoHS一些需要确定的问题,国家政策由信息产业部、发展改革委、商务部、海关总署、工商总局、质检总局、环保总局联合制定的电子信息产品污染控制管理办法（以下简称管理办法）已于2006年2月28日正式颁布，2007年3月1日施行。该 管理办法共分为四章二十七条，从电子信息产品生产时产品及包装物的设计、材料
23、和工艺的选择、技术的采用，标注产品中有毒有害物质的名称、含量和可否回收利用、电子信息产品环保使用期限，以及电子信息产品生产者、销售者和进口者应负责任等方面做出了具体规定。管理办法确定了对电子信息产品中含有的铅、汞、镉、六价铬和多溴联苯（PBB）、多溴二苯醚（PBDE）等六种有毒有害物质的控制采用目录管理的方式，循序渐进地推进禁止或限制其使用。1、SJ/T 11363:2007 电子信息产品中有毒有害物质的限量要求 2、SJ/T 11364:2007 电子信息产品污染控制标识要求3、SJ/T 11365:2007 电子信息产品中有毒有害物质的检测方法,1.5 China RoHS 我国的对策,1
24、.6 测试设备简介,PAHs are formed during the incomplete burning of coal,oil and gas,garbage,or other organic substances.They can also be found in substances such as crude oil,coal,creosote,and road/roofing tar.non-purified mineral oil plastizer for rubber,mould release agent oil,glue,dyestuff/pigment,solven
25、t,some raw material of intermediate of some chemicals.多环芳烃是一组化学物质，它们是由未经完全燃烧的煤、油和气、垃圾、或是其他有机物质形成的.它们还可以在一些物质中，如原油、煤、杂芬油、和焦油（沥青）、不纯的橡胶增塑剂矿物油、脱模剂油、胶水、颜料染料、溶剂残留、一些化学物质中间体的原料。,二、PAHs多环芳香烃化合物,PAHs are a group of chemicals,with 100group and 10,000substances,and 16 of PAHs were banned because of the carcin
26、ogenous suspicion.有超过100种、10,000个不同的多环芳烃化合物。绝大多数的多环芳烃在环境中不是单独存在，它们往往是两个或更多的多环芳烃的混合物。有16个被怀疑有致癌作用的PAHs被禁用。,Critical component 关键监控点 For material-skin contact potential materials(outside parts),main on:有皮肤直接接触的可能性（外部材料），主要是软性塑料、橡胶，黑色塑料，颜料喷塑涂层,Hazards 有害性 Carcinogenic potential 致癌 Hammer handle：2200 mg
27、/kg PAH，transfer to skin=3520 cigarettes.锤柄有2200毫克/公斤的PAHs,转移到皮肤的相当于3520根香烟。,Recall：In Germany and Belgium,from Jul,2005 to present,there were a at least US$90M products which were recalled,without any correlative law or directive.招回案例：在德国和比利时，从2005年7月到现在目前已经至少有9000万美金的产品 在没有明确指令和法律的情况下涉及被商家招回。,Legi
28、slation or requirement 法规或要求 Convention by representatives of BfR,TV-Rheinland,LGA,TV-Sd,Stiftung Warentest,and other concerned parties(representatives of trade,manufactures and other institutions)in Berlin,Aug.02,2005,see below:根据一些实验室、企业和政府机构的推荐，限制指标。,Directive 2005/69/ECDIRECTIVE 2005/69/EC OF TH
29、E EUROPEAN PARLIAMENT AND OF THE COUNCILof 16 November 2005欧洲议会及欧盟理事会已于2005 年11 月16 日在法国斯特拉斯堡签署了2005/69/EC 指令,并于同年12 月9 日发布,Potential Applications 用途PVC plasticizers or softeners 软性塑料的增塑剂 Hazards 危害might damage liver and kidneys 危害到肝和肾suspect to be carcinogenic 怀疑致癌suspect to cause damage to reprodu
30、ctive organs 怀疑危害生殖系统DIRECTIVE 2005/84/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 14 December，2005 By 16 July 2006 Member States shall adopt and publish the laws,regulations and administrative provisions necessary to comply with this Directive.They shall forthwith inform the Commission ther
31、eof.They shall apply these measures from 16 January 2007.“childcare article”means any product intended to facilitate sleep,relaxation,hygiene,the feeding of children or sucking on the part of children.欧盟在2005年12月27日的官方公报上公布第2005/84/EC号指令(原为1999/815/EC)，限制儿童玩具及其他用品的邻苯二甲酸盐含量。25个成员国必须于2006年7月16日前将该指令转化
32、为本国法例，并由2007年1月16日开始实行，所有制造商及进口商必须遵守有关法例。根据新指令，儿童护理用品是指任何有助儿童睡眠、放松、保持卫生，以及喂哺儿童或让儿童吸吮的产品，当中包括各种形状及类型奶嘴。,三、Phthalates邻苯二甲酸酯类增塑剂,And also,there was a law in US,California proposition65 to limit DEHP(100K products were recalled because of DEHP.现在在美国已经有严格的法律，加州65限制使用DEHP（0.01%)。中国的一些企业，由于电缆线中含有DEHP，已经有数十
33、万台产品被招回。,Critical component 关键监控点For all the relevant materials in the product,main for soft PVC and rubber.对产品上相应的材料，如软PVC和橡胶,Replacement 替代品-邻苯二甲酸二异丁酯，简称DIBP。可做DBP的替代品使用。-邻苯二甲酸二仲辛酯DCP,本品可作为聚氯乙烯、硝酸纤维素等树脂的增塑剂，通常可用作DOP的替代品，特别适用于增塑糊中，粘度稳定性好。,Test method 测试方法The plastic material is extracted by an extr
34、action solution,consisting of MTBE containing an internal standard DMP(dimethyl phthalate),and analyzed by GC/MS.样品用由叔丁基甲醚和二甲基邻苯二甲基内标溶液组成的溶剂进行萃取，用GC/MS测量。,In Europe and America,they all have the regulation for waste packages with the requirement on collection/recovery and limitation of hazardous sub
35、stances.European 94/62/EC,American CONEC(RTM-008),all had the chemical limited guideline:lead+cadmium+mercury+chrome(VI)100mg/kg.在欧洲和美国都有对于废弃物包装的回收和有害物质限制要求。欧洲的94/62/EC，美国的CONEC(RTM-008)要求，都有化学物质限制指标：铅镉汞六价铬 100mg/kg.随着RoHS的深入开展，废弃包装将越来越被重视；当然，风险明显要少很多。,四、包装指令,Test method:测试方法The same as RoHS 同RoHS一样
36、,Cartons for package products 包装产品所用纸盒Packaging for part transportation(e.g.handles,reels,sticks,magazines,bags,staples,sheetsetc.)用以运输的包装材料(如：手柄，卷轴，棍子，说明书，袋子，钉书针，纸张。等等),五、NP（As the surfactant）壬基酚（表面活性剂）,一.介绍 2003年，欧盟指令2003/53/EC正式颁布并要求所有成员国强制执行，包括德国从2005年1月开始正式执行。指令要求壬基苯酚“作为成品或原料，其浓度等于或大于0.1时，不得在市场
37、上销售或使用”二.限值,五、NP（As the surfactant）壬基酚（表面活性剂）,Test method 测试方法The sample is extracted by an extraction solution,consisting of n-hexane/acetone(1:1,v/v)and the internal standard 4-n-nonyl phenol.The extract is analyzed by GC/MS.样品用由正己烷/丙酮(1:1,V/V)和4-n-壬基酚组成的溶剂进行萃取，用GC/MS测量。,新电池指令：2006/66/EC,这个新的电池指令将
38、在指令发布当天实施。老的指令91/157/EC将在2008年9月26日被废止；同日欧盟成员国将把该指令转成本国的法律。Scope:all the batteries and accumulators,excluding used for security interests/arms/munitions and war materials 范围：所有电池，不包括：军事设备。,六、Battery requirement in EU 欧洲电池要求,“Chemical label”,Not apply to 不适用于:-emergency and alarm systems,应急和报警系统-Medi
39、cal equipment 医疗设备-Cordless power tools 手持式无线电动工具,-Legislation 法律限制-Japan Law Concerning the Examination and Regulation of Manufacture etc.of Chemical Substances 日本化审法-German Chemical Prohibition Regulation(ChemVerbotsV)(德国)多氯联苯(PCBs)是一系列不同含氯量的同系物的混合物。自1930年起，多氯联苯被广泛用于各种工业用途。他们由两个由碳离子联结的苯环组成，而氯离子替代苯
40、环上若干或所有10个碳离子。鹿特丹公约,以及在2001年签署的有关可持续有机污染物（POPs）的斯德哥尔摩国际公约，为消除多氯联苯污染提供了动力。全球环境基金等国际组织正在为有效实施可持续有机污染物国际公约，积极提供技术和经济的帮助，旨在2025年前消除所有多氯联苯污染物,七、PCBs&PCTs 多氯联苯和多氯三苯,Chemical test method Extraction by relevant solvents,and measured by GC-MS or GC-ECD用相应的溶剂萃取，用气相色谱质谱联用仪或气相色谱电子捕获检测器的测试方法定量 Extraction method:
41、soxhlet,microwave,hot-block or ultrosonic bath,etc 萃取的方法：索氏，微波，电热块或超声波，等。,-Potential Applications 用途 Flame retardant 阻燃剂 agent of the capacitance oil 电容油的添加剂 antistatic 抗静电 Pesticide 杀虫剂-Hazards 危害 carcinogenic 致癌 Discomfort on Intestines and stomach 致肠胃不适 Skin disease 皮肤病,It is always the mixture,a
42、nd it contains 75 iso compounds.它通常是混合物,包括75个异构体 Potential Applications 用途 Flame retardant 阻燃剂 anti-mold for wood 木材抗霉剂 additive of the lube 润滑油的添加剂 agent of the capacitance oil 电容油的添加剂-Hazards 危害 bio-accumulate 生物毒性积累 harmful to liver(penta-and hexa-)五氯化萘和六氯化萘对肝有害,八、PCNs 多氯化萘,Legislation 法律限制-Japan
43、 Law Concerning the Examination and Regulation of Manufacture etc.of Chemical Substances 日本化审法,Chemical test method Extraction by relevant solvents,and measured by GC-MS or GC-ECD 用相应的溶剂萃取，用气相色谱质谱联用仪或气相色谱电子捕获检测器的 测试方法定量 Extraction method:soxhlet,microwave,hot-block or ultrosonic bath,etc 萃取的方法：索氏，微波
44、，电热块或超声波，等。,九、ODCs,CFC&HCFC 臭氧层消耗物质,氟氯化碳/氢氟氯化碳,Legislation 法规-EU law:No 2037/2000;Potential Applications 用途 most of ODCs are fluorides,几乎所有的臭氧消耗层物质是氟化物,Vesicant or for plastic 塑料的发泡剂Propellants or solvent for dry cleaning agent,cleaning agent 干洗剂和清洁/清洗剂溶剂的抛射剂.Refrigerants 制冷剂Lubricants 润滑剂 Hazards 危
45、害Deplete ozone,and harmful to environment;危害环境,消耗臭氧层,致使紫外线直接穿透照射.Critical Components 主要监控部件Vesicant plastic 发泡塑胶,Chemical test method Measured by HS-GC-MS or GC-ELCD 用顶空气相色谱质谱联用仪或气相色谱电电解电导率检测器的定量,九、ODCs,CFC&HCFC 臭氧层消耗物质,氟氯化碳/氢氟氯化碳,十、MireX(Perchlordecone)灭蚁灵,Application 应用-Control ants quantity 控制蚂蚁数
46、量-1959-1972,used for the flame retardant of plastic,rubber,paint,pigment,paper and electrical products.1959-1972,用于塑料/橡胶/油漆/涂料/纸和电子产品的阻燃剂 Hazards 危害-Bio-accumulation 生物毒性积累-Be harmful to kidney and procreation system 对肾脏和生殖系统有害,Chemical test method Extraction by relevant solvents,and measured by GC-
47、MS or GC-ECD 用相应的溶剂萃取，用气相色谱质谱联用仪或气相色谱电子捕获监测器的 测试方法定量 Extraction method:soxhlet,microwave,hot-block or ultrosonic bath,etc 萃取的方法：索氏，微波，电热块或超声波，等。,十一、Short Chain Chlorinated Paraffins 短链氯化石蜡,Legislation 法规EU Directive 2002/45/EC(2003/549/EEC)Potential Applications 用途metal working fluids 金属加工fat liquor
48、ing product for leather 皮革上光油plasticizers for PVC 聚氯乙稀塑料的增塑剂flame retardants in textiles,rubber 纺织品和橡胶的阻燃剂 Hazards 危害highly accumulative and toxic in aquatic organisms 对水生物体有高的毒性积累和毒性possible to be intake by human 对人高的摄入可能性Molecule formula 分子式:CnH2n+2-mClm n-15 m-7,Test method 测试方法 Extraction by rel
49、evant solvents,and measured by GC-MS or GC-ECD 用相应的溶剂萃取，用气相色谱质谱联用仪或气相色谱电子捕获监测器的 测试方法定量,Legislation 法规EU Directive 91/173/EECGerman Chemical Prohibition Regulation(ChemVerbotsV)Swiss Ordinance relating to environmentally hazardous substances&various national laws Potential Applications 用途preservative
50、(fungicide)for wood,leather&textiles 木材/皮革和纺织品的防腐剂fungicide for the impregnation of heavy duty textiles 杀真菌剂bactericide for tanning&paper pulp industry 杀菌剂Hazards 危害Carcinogenic 致癌skin&oral toxic,toxic to aquatic organisms 皮肤和口腔危害,对水生物的危害environmental pollutant,sewage emits dioxins when exposed to t
