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1、氨基酸表面活性剂的市场现状及应用突破Market analysis and application breakthrough of amino acid surfactants广州天赐高新材料股份有限公司Guangzhou Tinci Materials Technology Co. Ltd.毛华丽 Lily Mao 2014.01.11,WWW,个人简介 Introduction,毛华丽 Lily Mao2009年毕业于浙江工业大学，专业为微生物与生化药学，获得硕士学位。 Graduated from Zhejiang University of Technology with Master
2、s degree for Microbiology & Biochemical Pharmacy at 2009. 毕业后在国内某知名日化企业从事日化产品研发，现任天赐日化事业部技术服务工程师，负责氨基酸类表面活性剂的应用及推广。 Served in a famous personal care company for personal care products research before, now serve in Tinci personal care department as technical service engineer for application and promo
3、tion of amino acid surfactants. 联系方式Tel：15989228970 邮箱Email：,目录,氨基酸表面活性剂的市场现状分析Market analysis of amino acid surfactants,1,什么是氨基酸表面活性剂？Amino acid surfactants introduction,氨基酸表面活性剂在洗发香波中的应用及选择Application and optimal solution for amino acid surfactants,结晶型氨基酸洁面膏介绍及推广 Introduction of crystallized amino
4、 acid facial cleanser,CONTENTS,2,3,4,1、氨基酸表面活性剂的市场现状分析Market analysis of amino acid surfactants,氨基酸表面活性剂的市场应用分类及选择Market analysis and optimal solution of amino acid surfactants,数据来源Source：GNPD, 2010.9-2012.9,全球范围内，含氨基酸表面活性剂的产品的前5公司 Top 5 companies of amino acid surfactants consumption (Global),数据来源：
5、GNPD, 2010.9-2012.9,氨基酸表面活性剂应用区域全球前7使用氨基酸表面活性剂的国家（2011.1-2012.12）Application region of amino acid surfactants Top 7 countries in amino acid surfactants consumption,Italia,45,5,Thailand,17,7,椰油酰甘氨酸钾(全球，国家)Application region of Potassium Cocoyl Glycinate (Global),数据来源：GNPD，162个新品，2010.10-2012.10Source
6、: GNPD, 162 new products, 2010.10-2012.10,氨基酸表面活性剂在个人护理品（新品）中应用占有率 Amino acid surfactants market share in new products,数据来源Source： GNPD, 2008.9-2013.9,2、什么是氨基酸表面活性剂？ Amino acid surfactants introduction,氨基酸类表面活性剂的结构组成Structure and composition of amino acid surfactants,氨基酸类表面活性剂典型反应,1、酰氯的合成 Synthesis
7、ofAcyl chloride,2、脂肪酰氨基酸钠的合成 Synthesis of Acyl amino acid-type surfactant,肌氨酸类Sarcosine,谷氨酸类Glutamic acid,甘氨酸类Glycine,氨基酸表面活性剂合成工艺Manufacturing process of amino acid surfactants,Fatty acyl chloride + Amine base salts,Amino acidsurfactant,Back acid and reduce salt content,pH Adjustment,Spray drying,F
8、laking-product,氨基酸表面活性剂反应副产物By products of amino acid surfactans,反应过程中采用氨基酸盐过量Extra addition of sodium of amino acid0.1%,适量无机盐可增加氨基酸表活溶液的透明性；在配方应用时，同样可以辅助增稠Appropriate amount of salt will increase the clarity of amino acid surfactant solutionShows auxiliary thickening ability 0.5%,皂含量高，透明性差，溶液粘度高，易增
9、稠；做洁面膏类产品，配方容易做；皂含量低，膏体偏硬，突变温度窄，膏体较粗High soap content leads to low clarity, high viscosity and easy to increase viscosity; it is easy to get facial cleanser; low soap content leads to narrow changing temperature range and rough appearance.1.5%,氨基酸表面活性剂在不同pH条件下的起泡性能Foamability of amino acid surfactan
10、ts at different pH,1、月桂酰肌氨酸钠pH在5-9.5区间内均有良好的起泡性能，酸性条件下更佳.Sodium Lauroyl Sarcosinate shows excellent foamability at pH 5-9.5, and in acid condition is better.2、椰油酰甘氨酸钾在pH7时具有良好的起泡效果，pH中性条件下有较好的耐硬水性能.Potassium Cocoyl Glycinate shows excellent foamability when pH7, and shows excellent hard water resist
11、ance in neutral condition.,测试方法：SITA 泡沫仪，900rpm，30s，样品浓度：0.3%Test method： SITA Foam Tester，900rpm，30s，sample concentration: 0.3%,氨基酸表面活性剂在不同pH条件下的起泡性能Foamability of amino acid surfactants at different pH,月桂酰谷氨酸钠在酸性条件下起泡性能优异，当pH7时，其在硬水中形成月桂酰谷氨酸钙反而有较优异的表面活性。Sodium Lauroyl Glutamate shows excellent foa
12、mability in acid condition, when pH7, it shows excellent surface activity for the generation of Calcium Lauroyl Glutamate.,月桂酰谷氨酸钠与脂肪酸复配泡沫性能Foamability of Sodium Lauroyl Glutamate combined with fatty acid,泡沫质量评价方法：配制10%的AMIN LGNa溶液，加热至35，取此溶液4ml用双手搓15秒，拍照，观察泡沫的质与量。Test method: Prepare 10% Sodium Lau
13、royl Glutamate solution, heat to 35, take 4mL into hand and rub for 15s, photo it and compare the quality and quantity of the foam.,AMIN LGNa溶液 AMIN LGNa solution,AMIN LGNa添加1%十四酸 Add 1% myristicacid into AMIN LGNa solution,AMIN LGNa添加1%十二酸 Add 1%lauricacid into AMIN LGNa solution,AMIN LGNa添加1%混合酸十四
14、酸/十二酸=7：3 Add 1% myristic acid and lauricacid at the ratio 7:3 into AMIN LGNa solution,AMIN LGNa的泡沫舒适，细密、柔滑，呈乳脂状。与脂肪酸结合可改变泡沫的状态，添加混合脂肪酸可改变增加泡沫的质与量The foam of AMIN LGNa is small, fine, smooth and creamy. When combined with fatty acid, the condition of the foam will change: the quality and quantity of
15、 the foam will be improved.,氨基酸表面活性剂乳化力性能测定及肤感Emulsifying ability tests and skin feeling,滋润感 Emollient,碱性Alkalinity,酸性Acidity,清爽感 Refreshing,AMIN,AMIN LG95F,AMIN GCK30,皂基Soap,AMIN LS30,测试方法：量筒法测试乳化力，30ml0.3%表面活性剂溶液与30ml白油混合震荡乳化，记录分层时间。Test method: Test with measuring cylinder, mix 30mL 0.3% surfacta
16、nt solution with 30mL white oil, record the time of phase separating.,氨基酸表面活性剂增稠解决方案Solution of viscosity increasing of amino acid surfactants,结论Conclusion:1、三种增稠方案在pH=4.5-5.5之间可以达到较好的增稠效果 The thickening ability is the best when pH is among 4.5-5.5 under the 3 condition2、泡沫性能，pH在5.0以下有更优的起泡性能 The fo
17、amability is better when pH is under 5.0,不同氨基酸表面活性剂在不同pH条件下的粘度Viscosity of different amino acid surfactants under different pH,pH,Viscosity/mPa.S,增稠机理？,氯化钠对含氨基酸表面活性剂体系粘度的影响The influence of NaCl for the viscosity of amino acid surfactants system,结论Conclusion：氯化钠对三种氨基酸表面活性剂的增稠性能：AMIN GCK30AMIN LS30AMI
18、N LG30The influence of NaCl for the viscosity of 3 kinds of amino acid surfactants: AMIN GCK30AMIN LS30AMIN LG30,研究洗发水在适当的固定pH条件下，氯化钠对含氨基酸表面活性剂体系粘度的影响Test the influence of NaCl for the viscosity of shampoo at specified pH,3、氨基酸表面活性剂在洗发香波中的应用及选择Application and optimal solution for amino acid surfacta
19、nts,日本无硫酸盐洗发水例 Sulfate-free shampoo in Japan,配料表：水，月桂基甜菜碱，甲基椰油酰基牛磺酸钠，椰油酰胺DEA，丁二醇，月桂酰胺丙基羟磺基甜菜碱，椰油酰谷氨酸二钠，吡罗克酮乙醇胺盐，甘草酸二钾，椰油酰胺MEA，椰油酰谷氨酸钠，提取物，聚季铵盐-10Ingredients:Water, Lauryl betaine, Sodium Methyl Cocoyl Taurate, Cocamide DEA, Butanediol, Cocamidopropyl Hydroxysultaine, Disodium cocoyl glutamate, Piroc
20、tone Olamine, Dipotassium Glycyrrhizinate, Cocamide MEA, Sodium Cocoyl Glutamate, Extract, Polyquaternium-10,市售洗发水泡沫对比Foamability comparison for marketed shampoo products,含有氨基酸表面活性剂洗发水的粘度对比Viscosity comparison of shampoo with amino acid surfactants,含有氨基酸表面活性剂的洗发水一般都粘度较低Normally, shampoo with amino a
21、cid surfactants appear low viscosity,洗发水的配方突破点Shampoo formula breakthrough,天然 Natural无硫酸盐 Sulfate-free温和 Mild低刺激 Low irritation洗护分开 Cleaning,conditioning separation,宝洁体系洗护二合一 P&G system-2 in 1,新领域 New field：无硫酸盐 Sulfate-free洗护二合一 Shampoo, conditioner 2 in 1,含有氨基酸表面活性剂洗发水的单一变数比较实验 Single variable com
22、parison test of shampoo with amino acid surfactants,在本实验配方中，肌氨酸盐比其它在梳理性方面有一定优势Sarcosinate surfactant shows better combing performance in this test.,Main ingredients: AES 9% or 12%, CAB35 3%, Amino acid surfactants 3% or 0%, PQ-10 0.5%,Sodium Cocoyl Glutamate,Sodium Cocoyl Glycinate,Sodium Lauroyl Sa
23、rcosinate,Blank,Untreated(Wet Hair),Before rinse,After rinse,After dry,无硫酸盐洗发水 Sulfate-free shampoo主要成分 Main ingredients：卡波姆380 Carbomer 380椰油酰胺丙基羟基磺基甜菜碱Cocamidopropyl Hydroxysultaine月桂酰肌氨酸钠 Sodium Lauroyl Sarcosinate月桂酰谷氨酸钠 Sodium Lauroyl Glutamate聚季铵盐-10 Polyquaternium-10乳化硅油 Silicone emulsion防腐剂
24、Preservative香精 Fragrance,粘度 Viscosity：5,000-10,000 成本 Cost：7-8 RMB/kg,无硫酸盐氨基酸洗发水的开发参考配方框架Reference formula for sulfate-free amino acid surfactants shampoo,无硫酸盐氨基酸洗发水与市售某产品对比Comparison of sulfate-free amino acid surfactants shampoo with marketed product,无硫酸盐氨基酸洗发水与市售某产品对比Comparison of sulfate-free am
25、ino acid surfactants shampoo with marketed product,4、结晶型氨基酸洁面膏介绍 Introduction of crystallized amino acid facial cleanser,结晶型氨基酸洁面膏 Crystallized amino acid facial cleanser,固体（结晶）与液体混合 Mixture of solid(crystal) and liquid,v,结晶 Crystal,表面活性剂饱和溶液 Saturated surfactants solution,室温Room temperature 80-50 4
26、5,Mix solid & liquid,Uniform liquid,Crystallize solid,结晶型洁面膏中主次表活的选择Choice of primary / secondary surfactants in crystallized amino acid facial cleanser,典型的结晶型洁面膏配方 Typical formula of crystallized amino acid facial cleanser ：表面活性剂 Surfactants: 15-30% 多元醇 Polyol: 20-40%- 甘油 、山梨醇 、1,3-丁二醇、丙二醇、PEG-6等 G
27、lycinate, sorbitol, butanediol, propyleneglycol, etc.水 Water: 30-40%表面活性剂的选择 Choice of surfactants ：1、用液体的氨基酸表面活性剂比较难做膏状的洁面产品 Liquid amino acid surfactants are hard to make paste facial cleanser2、粉末、片状、颗粒状、糊状 Powder, flake, granular, paste3、溶解性：偏低 Solubility: low,结晶型氨基酸洁面膏应用例Sample of crystallized a
28、mino acid facial cleanser,配料表：水，月桂酰谷氨酸钠，丙二醇，PEG-150硬脂酸酯，半乳糖酵母样菌发酵产物滤液，PCA钠，乙二醇硬脂酸酯，椰油酰胺MEA，丁二醇，提取物等 Ingredients:Water, Sodium Lauroyl Glutamate, Propylene Glycol, PEG-150 Stearate, Galactomyces Ferment Filtrate, Sodium PCA, Glycol Stearate, Cocamide MEA, Butanediol, Extract, etc.,SK-II柔肤洁面乳 SK-II Fa
29、cial treatment cleanser,上市时间 Time-to-market：2010.12120.0g82.71,天赐纯氨基酸洁面膏参考框架Reference formula for Tinci amino acid facial cleanser,纯氨基酸洁面膏 Amino acid facial cleanser主要成分 Main ingredients：月桂酰谷氨酸钠 Sodium Lauroyl Glutamate月桂酰肌氨酸钠 Sodium Lauroyl Sarcosinate多元醇 Polyol脂肪酸 Fatty acid珠光剂 Pearling agent丙烯酸（酯
30、）类共聚物 Acrylates Copolymer氯化钠 Sodium Chloride防腐剂 Preservative香精 Fragrance,成本 Cost：22-25 RMB/kg结膏点 Crystallized temperature：45,纯氨基酸洁面膏参考工艺Reference manufacture process of amino acid facial cleanser,40水浴浸泡30分钟后，缓慢搅拌40 water bath for 30min, mix slowly,80-85,通冷凝水降温至55-60Cool to 55-60 with condensatewater
31、,丙烯酸（酯）类共聚物Acrylates Copolymer,结晶温度46-48Crystallize temperature 46-48,香精、防腐剂Preservative, fragrance,去离子水/AMIN LG95F/其他表活/多元醇D.I. water/AMIN LG95F/other surfactants/polyol,持续搅拌至室温，熟化至第二天，挤压灌装Constantly mix to room temperature, cure to the next day, packing,氨基酸洁面膏对比Comparison of amino acid facial clea
32、nsers,v,结晶 Crystal,表面活性剂饱和溶液Saturated surfactants solution,v,结晶 Crystal,表面活性剂饱和溶液Saturated surfactants solution,聚合物增稠剂Polymer thickner,纯氨基酸洁面膏(SKII) SK-II amino acid facial cleanser,天赐氨基酸洁面膏Tinci amino acid facial cleanser,洁面膏泡沫性能对比Foamability of amino acid facial cleansers,测试方法：SITA泡沫仪，900转/min，10s
33、/次，12次，称取样品2g至400g150ppm硬水 Test method: SITA bubble instrument, 900rpm, 10s * 12 times,add 2g sample into 400g 150ppm hard water,铺展及冲洗性能对比图 （室温18）Comparison of spreadability & rinsing ability (room temperature 18),0.5g样品 0.5g sample 涂抹三次 Rub for 3 times 起泡10秒 Foam for 10s 起泡20秒 Foam for 20s,Tinci am
34、ino acid facial cleanser,A marketed amino Acid facial cleanser,0.5g样品 0.5g sample 涂抹三次 Rub for 3 times 起泡10秒 Foam for 10s 起泡20秒 Foam for 20s,天赐氨基酸表面活性剂介绍Introduction of Tinci amino acid surfactants,氨基酸类表面活性剂Amino acid surfactants,月桂酰肌氨酸钠/月桂酰肌氨酸TEA盐Sodium Lauroyl Sarcosinate / TEA Lauroyl SarcosinateAMIN LS30 、AMIN LSNa、AMINLST30,椰油酰甘氨酸钾/椰油酰甘氨酸钠Potassium Cocoyl Glycinate / Sodium Cocoyl GlycinateAMIN GCK30、AMIN GC30、AMIN GCNa,月桂酰谷氨酸钠/椰油酰谷氨酸钾Sodium Lauroyl Glutamate / Potassium Cocoyl Glutamate AMIN LG30、AMIN LGNa、AMIN LG95F、AMIN CGK30,ThanksQ&A,
