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1、一、什么是玻璃纤维I.What is fiberglass?,材料分类 Material Category 产品品种 Product category主要性能 Main properties主要产品 Main products,1、材料分类 Material category,Steel钢铁 Metal 金属 Nonferrous metals有色金属 Organic materials有机材料Materials Fiberglass玻璃纤维材料 FRP/High performance composites Nonmetal Special glass/deep-processed glas
2、s 非金属 Inorganic Special ceramic materials Artificial crystal 无机材料 Synthetic mica Laser crystal Special cementing material,2、产品品种Product category,Medium-Alkali fiberglass(C)中碱 Continuous fiberglass Alkali-free fiberglass(E)无碱 连续玻璃纤维 High-Alkali fiberglass(A)高碱 Staple fiberglass&glass wool玻璃棉Fiberglas
3、s玻璃纤维 High-strength fiberglass(S)高强 High-modulus fiberglass(M)高模量 High-silica fiberglass高硅氧 Special fiberglass Alkali&corrosion resistant fiberglass 抗碱 特种玻璃纤维 Optical communication fiberglass光通信 Light-guide fiberglass光导,3、玻璃材料 Glass-making materials,中碱玻璃原料 C-glass raw materials中碱玻璃球 C-glass marble中碱
4、玻璃粉料 C-glass batch中碱废丝 C-glass recycled waste fiber无碱玻璃原料 E-glass raw materials无碱玻璃球 E-glass marble无碱玻璃粉料 E-glass batch无碱废丝 E-glass recycled waster fiber,3.1 中碱玻璃粉料C-glass Raw materials,石英砂 Quartz sand:SiO2钠长石 Albite:AL2O3、Na2O白云石 Dolomite:CaO MgO 石灰石 Limestone:CaO 莹石 Fluorspar:CaF2 纯碱 Soda ash:Na2C
5、O3 硝酸钠 Sodium nitrate:NaNO3 无水硫酸钠 Anhydrous sodium sulfate:Na2SO4 氧化铈 Ceria:CeO2,3.2 无碱玻璃粉料 E-Glass raw materials,高岭土/叶腊石 Clay/Pyrophyllite:AL2O3、SiO2硼钙石 Colemanite:B2O3、CaO石灰石 Limestone:CaO 莹石 Fluorspar:CaF2、SiO2、CaCO3 石英砂 Quartz sand:SiO2纯碱 Soda ash:Na2CO3 无水硫酸钠 Anhydrous sodium sulfate:Na2SO4,3.3
6、 玻璃成分 Glass composition,3.3 成分与作用 Components and their functions,氧化硅SiO2:物质基础、骨架 Basis and matrix氧化铝Al2O3:降析晶和膨胀系数,提高稳定性和强度 to reduce recrystallization and expansion coefficient and increase stability and strength 氧化钙氧化镁:降低高温时粘度,促进熔化、澄清、提高拉丝速度 CaO/MgO:To reduce viscosity at high temperature and prom
7、ote melting,refining and increase winding speed.氧化硼B2O氧化铁Fe2O3 碱金属;助熔,提高流动性 Na2O/K2O;To aid melting and increase fluidity,4、主要产品 Main products,合股无捻粗纱直接无捻粗纱短切原丝无捻粗纱布缝编短切毡短切原丝毡缝编复合毡细纱,4.1 主要产品合股无捻粗纱 Main products Assembled roving,喷射 Spray up Roving(SP)缠绕 Filament winding roving(FW)拉挤 Pultrusion(PL)SMC
8、 roving(Roving for SMC)HOBAS管道 Roving for HOBAS pipes(HS)膨体 Textured roving(BY)透明板材 Panel roving(TS)热塑性增强 Roving for thermoplastics(RP)Roving for GMT(GMT),4.2 主要产品直接无捻粗纱 Main products-direct roving,缠绕 Filament winding roving(FW)拉挤 Pultrusion roving(PL)织布 Roving for woven roving(WR),4.3 主要产品短切原丝 Main
9、 products Chopped strands,团状模塑料 Bulk molding compound(BM)热塑性增强 Thermoplastic reinforcement(TP)湿法短切 Wet chop(WS)增强水泥 Reinforced cement(RC),4.4 主要产品布毡 Main products fabric&mat,无捻粗纱布 Woven rovingEWR 缝编短切毡Stitched chopped strand matEMK 短切原丝毡Chopped strand matEMC 缝编复合毡Stitched combo matEMK(0,90),4.5 主要产品
10、其它 Main products-Others,细纱Continuous filament yarn一般指单纤维直径9微米以下的玻璃纤维纱,包括G75纱、D450纱、E225纱等,织成7628布、2116布、1080布等。主要用于电子行业,增强覆铜板基板,部份为工业用布。,二、玻璃纤维行业的历史 II.History of fiberglass industry,国际发展 International development国内发展 Domestic development市场竞争 Market competition行业现状 Industry current status,1、国际发展 Int
11、ernational development,2000多年前,古埃及手工拉制玻纤做装饰材料;Over 2000 years ago,Egyptians manually made fiberglass as ornament material20世纪30年代,美国发明了铂坩埚拉制工艺技术;In the 1930s,Americans invented the technology of producing fiberglass with platinum crucibles1938年美国成立OWENS CORNING,具有工业性规模,用于绝缘材料;In 1938 Owens Corning C
12、o was established in USA which had a industrial scale of fiberglass production for insulation application.二战后工业普及,成立了圣哥本(法)、皮尔金顿(英)、日东纺(日)等;After World War II,the industrial production of fiberglass became popular and St.Gobain(France),Pilkington(Great Britain),Nittobo(Japan)started to produce fiber
13、glass.19591960年,OWENS CORNING和PPG公司相继建成了玻璃纤维池窑。In 1959 and 1960,Owens Corning and PPG built fiberglass furnaces.,2、国内发展Domestic development,20世纪50年代后期,我国玻璃纤维工业诞生,采用陶土坩埚法和镍铬合金孔板法生产;In late 1950s,the fiberglass industry started in China and the fiberglass then was produced with clay crucibles and nick
14、el-chrome alloy nozzle plates20世纪60年代中期,研制成功代铂坩埚法生产工艺;In the middle of 1960s,the platinum-substitute crucible process was invented20世纪90年代初,池窑法开始在中国普及。In the 1990s,the fiberglass furnaces became popular in China,3、市场竞争 Market competitors,国际竞争对手欧文斯.康宁(美)、PPG(美)、圣哥本(法)International competitors Owens C
15、orning,PPG,St.Gobain国内竞争对手巨石、泰山、重庆 Domestic competitors:Jushi,Taishan fiberglass,CPIC,4、行业现状 Industry current status,奠基于上世纪30年代末,已成独立工业体系。The industry established itself in 1930s and has formed into an independent industry system.目前有数千个品种与规格、5万多种用途,成为现代工业材料家族中重要的一员。At present there are thousands of
16、product types and specifications and over 50,000 applications and fiberglass has become an important member in the modern industrial material family.,三、玻璃纤维有什么用处?III.What is fiberglass for?,交通运输 Transportation建筑建材 Construction电气工业 Electrical机械工业 Engineering石油化工 Petroleum&chemical休闲文化 Leisure and sports国防科技 Defence,四、玻璃纤维怎么做出来的?IV.How is fiberglass produced?,一、代铂炉生产工艺,四、玻璃纤维怎么做出来的?IV.How is fiberglass produced?,二、波歇炉生产工艺,四、玻璃纤维怎么做出来的?IV.How is fiberglass produced?,配料 Batch熔化 Melting拉丝 Fiberforming烘干 Drying,络纱 Roving织布 Weaving制毡 Mat production捻线 Twisting短切 Chopping,三、单元窑生产工艺,